Tetrahedron Letters p. 7895 - 7898 (1992)
Update date:2022-08-03
Topics:
Tsai, Yeun-Min
Ke, Bor-Wen
Yang, Chain-Ting
Lin, Chao-Hsiung
Intramolecular addition of α-sulfonyl radicals to triple bonds followed by addition of tin radicals to the resulting allylsulfones gave pyrrolizidine skeletons. Subsequent manipulations led to a formal synthesis of (±)-supinidine.
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