Synthesis of (t-2-Benzyloxymethyl-t-3-hydroxy-r-1-methoxycarbonyl)-tetrahydrofuran from an arabino-Lactone Triflate with K2CO3-MeOH

DOI: 10.1039/P19920003003

Source and publish data:

Journal of the Chemical Society. Perkin transactions I p. 3003 - 3004 (1992)

Update date:2022-07-31

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Authors:

Izawa, Takao

Nakayama, Kumiko

Nishiyama, Shigeru

Yamamura, Shosuke

Kato, Kuniki

Takita, Tomohisa

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Article abstract of DOI:10.1039/P19920003003

The arabino-lactone triflate 4 reacts with K2CO3 in MeOH to give the oxetane ester 5 and the tetrahydrofuran ester 6 in a ratio dependent upon the reaction temperature.

Full text of DOI:10.1039/P19920003003

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Product name:(2R,3R,4S)-3-Benzyloxymethyl-4-hydroxy-tetrahydro-furan-2-carboxylic acid methyl ester

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