New, Chiral Silylated Organophosphorus(III) Reagents: Syntheses and Applications in the Asymmetric Phosphorylation of Aldehydes

DOI: 10.1039/c39920001771

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 1771 - 1773 (1992)

Update date:2022-08-05

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Authors:

Sum, Vivienne

Davies, Anita J.

Kee, Terence P.

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Article abstract of DOI:10.1039/c39920001771

The new silylated organophosphorus(III) compounds, (1R,2S)-(O,N-ephedrine)POSiR3 (R3=Ph3, t-BuMe2, Et3) have been synthesised and shown to react with benzaldehyde to afford the phosphonate esters (1R,2S)-(O,N-ephedrine)P(=O)CHPh(OSiR3) with good stereosel

Full text of DOI:10.1039/c39920001771

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