Acyclic diastereocontrol and asymmetric transmission via anionic oxy-Cope rearrangement. Synthesis of key precursors of (+)-faranal and (-)-antirhine

DOI: 10.1016/S0040-4020(01)86283-9

Source and publish data:

Tetrahedron p. 1025 - 1042 (1993)

Update date:2022-09-26

Topics:

Authors:

Wei Wei

Tomooka Tomooka

Nakai Nakai

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/S0040-4020(01)86283-9

The anionic oxy-Cope rearrangements of acyclic 1,5-dien-3-ols, when their stereochemistries are properly designated, are shown to proceed with a high level of diastereoselection and asymmetric transmission. The utility of the acyclic oxy-Cope variants is

Full text of DOI:10.1016/S0040-4020(01)86283-9

Products guided by the article

Product name:Toluene-4-sulfonic acid (Z)-(S)-6-tert-butoxy-2-hydroxy-hex-3-enyl ester

Cas No:147589-62-6

R&D Labs maybe for 147589-62-6

SYN Pharma Co., Ltd

Contact:86-21 60347964

Address:No.1304, West Meilong Road, Minhang District, Shanghai, China
Tianjin Bright Future Technology Co., Ltd

Contact:0086-22-58016666

Address:NO.136 DongTeng Lake Street Tianjin Economic and Technology Development Area,Tainjin,China
Shaanxi Sinuote Biotech Co.,Ltd

Contact:+86-29-68859685

Address:No 18,Taiyuan Road ,Xi'an city ,China
Shandong Loyal Chemical industrial Co.,Ltd

Contact:0533-7451788

Address:Linzi Chemical Industrial Park, Zibo, Shandong Province
Tianjin SPHINX SCIENTIFIC LAB.

Contact:+86-022-66211289

Address:Tianda high-tech Park. No.80,the 4th Avenue

Relevant to this article

A general synthetic strategy for 1,3-dihydro-2,1,3-benzothiadiazole 2,2-dioxides (benzosulfamides)

Doi:10.1016/j.tetlet.2010.07.173
(2010)
Deuterium isotope effects on ¹³C and ¹⁵N chemical shifts of intramolecularly hydrogen-bonded enaminocarbonyl derivatives of Meldrum's and Tetronic acid

Doi:10.1016/j.molstruc.2010.03.059
(2010)
TNF Induced Switching of Columnar Rectangular to Hexagonal Assemblies in a New Class of Triphenylene-Based Room Temperature Discotic Liquid Crystals

Doi:10.1021/acs.jpcb.7b06737
(2017)
Preparative and mechanistic studies toward the rational development of catalytic, enantioselective selenoetherification reactions

Doi:10.1021/ja106837b
(2010)
Synthesis of enantioenriched indolopiperazinones via iridium(i) n-heterocyclic carbene complex catalyzed asymmetric intramolecular allylic amination reaction

Doi:10.3987/COM-16-S(S)19
(2017)
Synthesis, X-ray structure and electrochemical oxidation of palladium(II) complexes of ferrocenyldiphenylphosphine

Doi:10.1039/c0dt00016g
(2010)

Article Doi