Acyclic diastereocontrol and asymmetric transmission via anionic oxy-Cope rearrangement. Synthesis of key precursors of (+)-faranal and (-)-antirhine

DOI: 10.1016/S0040-4020(01)86283-9

Source and publish data:

Tetrahedron p. 1025 - 1042 (1993)

Update date:2022-09-26

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Authors:

Wei Wei

Tomooka Tomooka

Nakai Nakai

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Article abstract of DOI:10.1016/S0040-4020(01)86283-9

The anionic oxy-Cope rearrangements of acyclic 1,5-dien-3-ols, when their stereochemistries are properly designated, are shown to proceed with a high level of diastereoselection and asymmetric transmission. The utility of the acyclic oxy-Cope variants is

Full text of DOI:10.1016/S0040-4020(01)86283-9

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