Reaction of dichlorocarbene with 1,2-dihydro 1,2 λ3-azaphosphinine-boranes: Dichlorocyclopropanation and insertion into boron-hydrogen bond

DOI: 10.1016/S0040-4039(00)60575-0

Source and publish data:

Tetrahedron Letters p. 311 - 314 (1993)

Update date:2022-08-03

Topics:

Authors:

Bedel Bedel

Foucaud Foucaud

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Article abstract of DOI:10.1016/S0040-4039(00)60575-0

The reaction of dichlorocarbene with 1,2-dihydro 1,2 λ³-azaphosphinine-boranes gave regioselective dichlorocyclopropanation and also insertion of dichlorocarbene into B-H bond. This insertion reaction is general and can be a useful synthetic method for the preparation of functionalized phosphine-boranes.

Full text of DOI:10.1016/S0040-4039(00)60575-0

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