Samarium Dibromide, an Efficient Reagent for the Pinacol Coupling Reactions.

DOI: 10.1016/S0040-4039(00)77601-5

Source and publish data:

Tetrahedron Letters p. 2311 - 2314 (1993)

Update date:2022-08-04

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Authors:

Lebrun, Alain

Namy, Jean-Louis

Kagan, Henri B.

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Article abstract of DOI:10.1016/S0040-4039(00)77601-5

The preparation of SmBr2 from Sm2O3 is described.This samarium (II) compound is a powerful one electron reductant able to very efficiently mediate pinacolic couplings.Cross couplings are effective in some cases, for example a chiral diol can be obtained from benzophenone and camphor.Intramolecular pinacolization of a diketone has been performed.

Full text of DOI:10.1016/S0040-4039(00)77601-5

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