Tetrahedron Letters p. 2323 - 2326 (1993)
Update date:2022-07-30
Topics:
Ikeda
Oikawa
Miyashi
The 9,10-dicyanoanthracene (DCA)-sensitized electron-transfer photoreactions of E- and Z-1,5-diphenyl-1,5-hexadienes (E-2 and Z-2) gave a mixture of endo- and exo-1,5-diphenylbicyclo [2.1.1]hexanes (endo-3 and exo-3) while 2,4-diphenyl-1,5-hexadiene (1) underwent the Cope rearrangements to E-2, showing significant substitution effects on cyclization of 1,5-hexadiene cation radicals.
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