
Organic Letters p. 5592 - 5596 (2018)
Update date:2022-09-26
Topics:
Sun, Qi
Li, Linge
Liu, Liyan
Guan, Qianqian
Yang, Yu
Zha, Zhenggen
Wang, Zhiyong
A copper(I)-catalyzed geminal difunctionalization of terminal alkynes was developed via a carbene migratory insertion and an addition of a sulfonyl anion to the triple bond at the same time under mild reaction conditions, providing a variety of vinyl sulfones with good yields and excellent stereoselectivities.
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