Borole derivatives X. Syntheses of (η5-borole)metal complexes via borole ammonia adducts. Complexes of the chromium group metals and the crystal and molecular structures of tetracarbonyl 5-(1-phenylborole)>chromium and its molybden

Article abstract of DOI:10.1016/0022-328X(87)87155-3

The 1H-Borole ammonia adducts C4H4Br*NH3 (R=Me,Ph) (Ia,b) have been made by ammonia degradation of the (η⁵-borole)carbonyliodocobalt complexes (C4H4BR)Co(CO)2I (VIa,b).They are the simplest 1H-borole derivatives obtained to date, and have been