Radical Rearrangements of 2-O-(Diphenoxyphosphoryl)glycosyl Bromides

DOI: 10.1002/hlca.19930760426

Source and publish data:

Helvetica Chimica Acta p. 1687 - 1701 (1993)

Update date:2022-08-04

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Authors:

Koch, Andreas

Giese, Bernd

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Article abstract of DOI:10.1002/hlca.19930760426

A variety of 2-deoxy-1-O-diphenoxyphosphoryl-hexopyranoses were generated in situ by a radical 2->1 migration of the phosphate group.The structures of the reactive rearrangement products were fully elucidated by NMR spectroscopy.Rate constants for this ne

Full text of DOI:10.1002/hlca.19930760426

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