Journal of the Chemical Society. Chemical communications p. 1013 - 1014 (1995)
Update date:2022-08-03
Topics:
Akai, Shuji
Takeda, Yoshifumi
Iio, Kiyosei
Yoshida, Yutaka
Kita, Yasuyuki
Treatment of the p-sulfinylphenol derivatives 1 and 5 with trifluoroacetic anhydride causes a Pummerer-type rearrangement on aromatic rings and concomitant desulfurization to give 1:1 mixtures of the corresponding p-quinones and p-dihydroquinones, which are subjected to mild oxidation to provide high yields of p-quinones 3 and 7.
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