Total synthesis of (6R,8S)-cis-trikentrin B, (6R,8R)-trans-trikentrin B, and (6R,8R)-iso-trans-trikentrin B. determination of the absolute structures of the natural trikentrins B

DOI: 10.1016/S0040-4039(00)74096-2

Source and publish data:

Tetrahedron Letters p. 4815 - 4818 (1993)

Update date:2022-08-04

Topics:

Authors:

Muratake, Hideaki

Seino, Takako

Natsume, Mitsutaka

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Article abstract of DOI:10.1016/S0040-4039(00)74096-2

The absolute structures of cis-trikentrin B, trans-trikentrin B, and iso-trans-trikentrin B were established to be 1, 2, and 3 by synthesizing the titled trikentrins 1,18b and 25 in an enantiospecific manner from a chirality-defined Diels-Alder adduct 7.

Full text of DOI:10.1016/S0040-4039(00)74096-2

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Product name:(6R,8R)-4-(3-butenyl)-6,8-dimethyl-1-(phenylsulfonyl)-1,6,7,8-tetrahydrocyclopentindole

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