Journal of Organic Chemistry p. 148 - 153 (1994)
Update date:2022-08-03
Topics:
Sakuragi, Akira
Shirai, Naohiro
Sato, Yoshiro
Kurono, Yukihisa
Hatano, Keiichiro
Fluoride ion induced desilylation of cis-2-methyl-1-(substituted phenyl)-2-<(trimethylsilyl)methyl>isoindolinium iodides cis-5 gave mixtures of the Sommelet-Hauser rearrangement products 7 and the Stevens products 8 in a ratio about 8.5:1.5.Similar treatments of the trans-isomer (trans-5) afforded exclusively 8.The pathways of the ylide rearrangement are discussed.
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