Tetrahedron Letters p. 5759 - 5762 (1994)
Update date:2022-07-31
Topics:
Omstein, Paul L.
Melikian, Anita
Martinelli, Michael J.
We report the preparation of a hydroisoquinoline intermediate potentially useful for the synthesis of some excitatory amino acid antagonists.The requisite stereochemistry is established by an intramolecular Diels-Alder reaction, and the absolute stereochemistry is ultimately derived from S-aspartic acid.Also reported is an efficient synthesis of methyl N-CBZ asparate β-aldehyde.
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