Novel Catalytic Metathesis of Substituted Olefins Promoted by Rhenium(I) Enolate Complexes

DOI: 10.1246/cl.1994.165

Source and publish data:

Chemistry Letters p. 165 - 166 (1994)

Update date:2022-07-31

Topics:

Authors:

Hirano, Masafumi

Hirai, Miwa

Ito, Yuji

Fukuoka, Atsushi

Komiya, Sanshiro

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1246/cl.1994.165

Rhenium(I) enolate complexes Re(NCCHCO2Et)(PMe2Ph)4 and Re(NCCHCO2Et)(NCCH2CO2Et)(PMe2Ph)4 are found to catalyze unique olefin metathesis reaction of tetracyanoethylene with ethyl α-cyanocinnamate to give 1,1-dicyano-2-phenylethylene and ethyl 2,3,3-tricyanopropenoate at room temperature.

Full text of DOI:10.1246/cl.1994.165

Products guided by the article

Product name:2-Propenoic acid, 2,3,3-tricyano-, ethyl ester

Cas No:153814-39-2

R&D Labs maybe for 153814-39-2

ABA Chemicals (Shanghai) Limited

Contact:021- 5115 9199-232

Address:Suite 18D, #201 Ningxia Road,
Shanghai Balmxy Pharmaceutical Co., Ltd

Contact:0086-21-24206007

Address:Room 402, 15#, No. 909 wangyue Road, shanghai, P. R. China
Hunan Haili Chemical Industry Co.,Ltd.

Contact:+86-731-85521860

Address:No.251, 2nd Section, Furong Road, Changsha,Hunan,China
Beijing Green Guardee Technology CO,.LTD

Contact:+86-10-69706062

Address:F2 BLdj,5 No.37 Chaoqian Road
PINGYUAN SIHUAN PHARMACEUTICAL CO., LTD

Contact:+86-531-55696072

Address:#2766,yinxiu Road, Economic Development Zone, Pingyuan Country, Shandong Province, China.

Relevant to this article

Chemo- and Regioselective Rhodium(I)-Catalyzed [2+2+2] Cycloaddition of Allenynes with Alkynes

Doi:10.1002/chem.201602239
(2016)
Alkyl transfer from C-C cleavage

Doi:10.1002/anie.201303696
(2013)
Doi:10.1021/jo01016a009
(1965)
The synthesis of 6,9-difluorobenzo[g]quinoline-5,10-dione. Displacements of the fluorides by diamines which lead to 6,9- bis[(aminoalkyl)amino]benzo[g]quinoline-5,10-diones

Doi:10.1002/jhet.5570300619
(1993)
Insights into the organocatalyzed synthesis of urethanes in supercritical carbon dioxide: An in Situ FTIR spectroscopic kinetic study

Doi:10.1002/cctc.201301002
(2014)
α-Isocyanatoacrylonitriles from alkylidene- or arylidenecyanoacetic acids; synthesis and reactions

Doi:10.1055/s-1994-25405
(1994)

Article Doi