Novel Catalytic Metathesis of Substituted Olefins Promoted by Rhenium(I) Enolate Complexes

DOI: 10.1246/cl.1994.165

Source and publish data:

Chemistry Letters p. 165 - 166 (1994)

Update date:2022-07-31

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Authors:

Hirano, Masafumi

Hirai, Miwa

Ito, Yuji

Fukuoka, Atsushi

Komiya, Sanshiro

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Article abstract of DOI:10.1246/cl.1994.165

Rhenium(I) enolate complexes Re(NCCHCO2Et)(PMe2Ph)4 and Re(NCCHCO2Et)(NCCH2CO2Et)(PMe2Ph)4 are found to catalyze unique olefin metathesis reaction of tetracyanoethylene with ethyl α-cyanocinnamate to give 1,1-dicyano-2-phenylethylene and ethyl 2,3,3-tricyanopropenoate at room temperature.

Full text of DOI:10.1246/cl.1994.165

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