The preparation and structures of Ph3AsGal3 and

DOI: 10.1016/0022-328X(94)87020-9

Source and publish data:

Journal of Organometallic Chemistry p. C4 - C6 (1994)

Update date:2022-07-29

Topics:

Authors:

Baker, L.-J.

Rickard, Clifton E.F.

Taylor, Michael J.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/0022-328X(94)87020-9

Colourless crystals of Ph3AsGaI3 (1) have been prepared by reaction of triphenylarsine with GaI3*OEt2 in diethyl ether.The structure of 1, in which the length of the As-Ga donor-acceptor bond is 2.490(2) Angstroem, has been determined by an X-ray diffraction study.In contact with the solvent phase, 1 is transformed into yellow crystals of , 2 which has been structurally characterised by Raman spectroscopy (As-I stretching at 196 cm^-1) and by X-ray diffraction.The salt 2 is the first arsenic(V) iodo complex to have been examined crystallographically; the As-I bond distance is 2.485(1) Angstroem.Key words: Gallium; Arsenic; Lewis acid-base adduct; Donor-acceptor

Full text of DOI:10.1016/0022-328X(94)87020-9

Products guided by the article

Product name:{(C₆H₅)3AsI}⁽¹⁺⁾*{GaI₄}^(1-)={(C₆H₅)3AsI}{GaI₄}

Cas No:154193-99-4

R&D Labs maybe for 154193-99-4

Ningbo Inno Pharmchem Co., Ltd.

Contact:86-574-87319282

Address:6F-5,NO.163 RUIQING RD.,NINGBO 315000 CHINA
Shanghai Dano Pharmaceutical Co.,Ld.(expird)

Contact:+86-592-6266840

Address:Building 1 Room 512, 720 Cailun Rd, Zhangjiang High-Tech Park, Shanghai 201203, China
AURORA CHEMICAL CO., LTD

Contact:86-532-68629711 13780605697

Address:NO 220 YANAN 3 ROAD,(POST ADMINISTRATION BUILDING),QINGDAO,CHINA
Shanghai Yudiao Chemistry Technology Co.,Ltd

Contact:0086-18964703211

Address:Building NO.5, NO.218,Rongtian Road,ganxiang town,Jinshan District,shanghai,201518,china
Lanling Hongchuang Flame Retardant Co., Ltd.

Contact:+86-531-68858132

Address:East Huafeichang Road, Cangshan County, Linyi, Shandong, China (Mainland)

Relevant to this article

FUNCTIONALIZED CHLOROENAMINES IN AMINOCYCLOPROPANE SYNTHESIS - XV. SYNTHESIS OF CONFORMATIONALLY RIGID ANALOGUES OF <1,4'-BIPIPERIDINE>-4'-CARBOXAMIDE - A COMMON PHARMACOPHORIC GROUP

Doi:10.1016/S0040-4020(01)81111-X
(1994)
Dispiroketals in synthesis (part 5): A new opportunity for oligosaccharide synthesis using differentially activated glycosyl donors and acceptors

Doi:10.1016/S0040-4039(00)61375-8
(1993)
Study of the structure-activity relationships of the acetogenin of annonaceae, muricatacin and analogues

Doi:10.1016/S0223-5234(97)83287-4
(1997)
Preparation of diazenes by electrophile C-coupling reactions of dry arenediazonium o-benzenedisulfonimides with Grignard reagents

Doi:10.1055/s-1998-6102
(1998)
Potential anxiolytic agents. Part 4: Novel orally-active N⁵-substituted pyrido[1,2-a]benzimidazoles with high GABA-A receptor affinity

Doi:10.1016/S0960-894X(02)00463-8
(2002)
Four-Component Reaction between Secondary Phosphines, Primary Amines, Aldehydes, and Chalcogens: A Facile Access to Functionalized α-Aminophosphine Chalcogenides

Doi:10.1055/s-0036-1588127
(2017)

Article Doi