Tetrahedron p. 5921 - 5928 (1995)
Update date:2022-09-26
Topics: NMR spectroscopy Chiral Enantiomeric excess (ee) Recrystallization Hydrolysis Mass spectrometry (MS) Enantioselective synthesis Nucleophilic addition Optical rotation Deprotection Asymmetric catalysis Resolution Diastereomers Chiral Auxiliary Synthetic intermediates
Cativiela
Diez-De-Villegas
Galvez
Lapena
A divergent stereoselective synthesis of R and S α-methylvaline from (2RS) (1S,2R,4R)-10-dicyclohexylsulfamoylisobornyl 2-cyano-3-methylbutanoate has been developed.
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Doi:10.1248/cpb.41.1459
(1993)Doi:10.1021/ja00090a002
(1994)Doi:10.1139/v94-036
(1994)Doi:10.1021/ja00086a060
(1994)Doi:10.3109/14756366.2012.746972
(2014)Doi:10.1002/chem.201203360
(2013)
