Syntheses and molecular and electronic structures of tris(arylimido)technetium(VI) and -(V) complexes derived from successive one-electron reductions of tris(arylimido)iodotechnetium(VII)

DOI: 10.1021/ja00088a018

Source and publish data:

Journal of the American Chemical Society p. 3813 - 3821 (1994)

Update date:2022-08-02

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Authors:

Burrell, Anthony K.

Clark, David L.

Gordon, Pamela L.

Sattelberger, Alfred P.

Bryan, Jeffrey C.

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Article abstract of DOI:10.1021/ja00088a018

Reduction Of Tc(NAr′)₃I (Ar′ = 2,6-dimethylphenyl) by 1 equiv of sodium generates the edge-bridged tetrahedral dimer complex Tc₂(NAr′)₄(μ-NAr′)₂ In contrast, reduction of the more sterically hindered Tc(NAr) View More

Full text of DOI:10.1021/ja00088a018

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