Enantioselective Synthesis of Indolizine Derivatives by Rearrangement-Cyclization of Isoxazoline-5-spirocyclopropanes

DOI: 10.1016/S0040-4020(01)81553-2

Source and publish data:

Tetrahedron p. 10629 - 10642 (1993)

Update date:2022-09-26

Topics:

Authors:

Occhiato, Ernesto G.

Guarna, Antonio

Spinetti, Laura Michela

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Article abstract of DOI:10.1016/S0040-4020(01)81553-2

(3S,7S,8aS)-3-Methyl-7-hydroxyoctahydroindolizine (13) was prepared with an enantiomeric excess of 74percent, in five steps starting from enantiomerically pure (S)-(+)-5-nitro-2-pentanol (5). (3S,5S,7S,8aS)-(-)-3-Methyl-5-phenyl-7-hydroxyoctahydroindolizi

Full text of DOI:10.1016/S0040-4020(01)81553-2

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