Synthetic Studies on Polypropionate Antibiotics Based on the Stereospecific Methylation of γ,δ-Epoxy Acrylates by Trimethylaluminum. A Highly Stereoselective Construction of the Eight Contiguous Chiral Centers of Ansa-chains of Rifamycins

DOI: 10.1016/S0040-4039(00)73733-6

Source and publish data:

Tetrahedron Letters p. 6285 - 6288 (1993)

Update date:2022-08-03

Topics: Chiral Centers Stereoselective construction

Authors:

Miyashita, Masaaki

Yoshihara, Kousei

Kawamine, Katsumi

Hoshino, Masahide

Irie, Hiroshi

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Article abstract of DOI:10.1016/S0040-4039(00)73733-6

A highly stereoselective construction of the eight contiguous chiral centers of ansa-chains of rifamycins has been accomplished by the iterative use of the stereospecific methylation of γ,δ-epoxy acrylates by trimethylaluminum which was recently developed

Full text of DOI:10.1016/S0040-4039(00)73733-6

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