Russian Chemical Bulletin p. 2286 - 2291 (1998)
Update date:2022-08-04
Topics:
Stepanov
Lozanova
Veselovsky
The alkaloid (-)-actinidine of the iridane series was synthesized using intramolecular [3+2] dipolar cycloaddition of silyl nitronates, generated from (3R/S,6S)-2,6-dimethyl-3-nitro-8-phenylthioocta-1,7E-and -1,7Z-dienes. The key nitro compounds were obtained from (-)-(S)-citronellol.
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