Synthesis and Charactirisation of Zirconium Complexes with the Diphosphinophosphide Ligands -P(CH2CH2PR2)2 (R = Me or Et); Crystal Structure of Bispentachlorohydridodizirconium(IV)

DOI: 10.1039/DT9940000977

Source and publish data:

Journal of the Chemical Society, Dalton Transactions p. 977 - 986 (1994)

Update date:2022-08-04

Topics:

Authors:

Danopoulos, Andreas A.

Edwards, Peter G.

Harman, Mary

Hursthoust, Michael B.

Parry, Julian S.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1039/DT9940000977

A new high-yield selective synthesis of the ditertiary phosphino secondary phosphines P(CH2CH2PR2)2H (R = Me or Et) has been developed.Following deprotonation, the multidentate anionic phosphides have been applied to the synthesis of new classes of zirconium and hafnium phosphides.New compounds of the form , , and -P(CH2CH2PMe2)2> are reported and are characterised by spectroscopic and analytical methods.The crystal structure of the hydrido complex has been determined and shows a binuclear structure containing bridging pphosphide and hydride ligands.

Full text of DOI:10.1039/DT9940000977

View Article Online / Journal Homepage / Table of Contents for this issue

View Article Online

Products guided by the article

Product name:Benzylbis(2-diethylphosphinoethyl)phosphine

Cas No:156267-60-6

R&D Labs maybe for 156267-60-6

Taimai Sanluck Pharmaceutical Co.,Ltd

Contact:86-592-7662921

Address:8D,No.186,Huarong Road,Huli,Xiamen,China
Anhui Qingyun Pharmaceutical and Chemical Co.,Ltd

Contact:+86-551-63633067

Address:Shuangfeng Road Hefei Anhui
Tianjin Chemsyntech Chemical Co., Ltd

Contact:+86-22-60872258

Address:Haitai green industry base in Tianjin, K1,5-601
Qingdao Kingway Pharmtech Co., Ltd.

Contact:86-532-87118899

Address:No. 88, Middle Haixi Road, Jiaonan City, Qingdao, China
QINGDAO TAOSIGN INTERNATIONAL TRADE CO.,LIMITED

Contact:+86-0532-82683616

Address:RM1402, Doublestar Seacoase 7#, No. 5 Guizhou Road, Qingdao, Shandong, China

Relevant to this article

Biomimetic Total Synthesis of Dysoxylum Alkaloids

Doi:10.1021/acs.joc.9b02093
(2019)
Doi:10.1016/S0022-328X(00)91048-9
(1967)
Investigating the effects of side chain length on the AIE properties of water-soluble TPE derivatives

Doi:10.1016/j.tetlet.2014.01.062
(2014)
Synthesis of Cryptochiral (R,R)-2,3-Dideuterooxirane as Stereochemical Reference Compound and Chemical Correlation with D-(+)-Glyceraldehyde

Doi:10.1002/ijch.201600111
(2016)
Reaction of 1,2,3-selenadiazoles with boranes

Doi:10.1007/s10593-007-0036-7
(2007)
ALLYLPALLADIUM(II) COMPLEXES DERIVED FROM 1,2,6-HEPTATRIENE AND 1,2,8-NONATRIENE

Doi:10.1016/0022-328X(84)85083-4
(1984)

Article Doi