Reaction of Diphenylketene with some Cyclohexa-3,5-diene-1,2-cis-diol Derivatives: Conversion of Chlorobenzene into Optically Active 2-Oxabicycloocten-3-one

DOI: 10.1039/c39940000803

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 803 - 804 (1994)

Update date:2022-08-04

Topics:

Authors:

Pittol, Carlos A.

Roberts, Stanley M.

Sutton, Peter W.

Williams, Julian O.

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Article abstract of DOI:10.1039/c39940000803

The dienes 11-15 react with diphenylketene to give mixtures of the corresponding <2 + 2>-adducts 16-20 and <4 + 2>-adducts 21-25: the isomers 19/24 were converted into the optically active lactone 26 in two steps.

Full text of DOI:10.1039/c39940000803

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