Journal of Organic Chemistry p. 4535 - 4541 (1994)
Update date:2022-07-31
Topics:
Davies, Huw M. L.
Hu, Baihua
Saikali, Elie
Bruzinski, Paul R.
Rhodium(II)-stabilized vinylcarbenoid intermediates display electrophic character at both the carbenoid site and the vinylogous position.The solvent and catalyst as well as the vinylcarbenoid structure have major effects on the regiochemical outcome of the reaction of vinylcarbenoids with alkenes and dienes.Reaction of vinylcarbenoids with vinyl ethers can lead to the formation of either cyclopropanes or cyclopentenes while reaction of vinylcarbenoids with cyclopentadiene can lead to the formation of either bicyclo<3.2.1>octadiene or bicyclo<2.2.1>heptene derivatives.
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Doi:10.1007/s11172-013-0168-0
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(1994)
