Journal of the Chemical Society, Dalton Transactions p. 466 - 471 (1981)
Update date:2022-07-29
Topics:
Newton, William J.
Tabner, Brian J.
The e.s.r. spectra of seven copper(II) dithiocarbamates have been recorded in chloroform-ethanol mixtures at room temperature and at 113 K.It has been found that the addition of a range of salts to these dithiocarbamates destroys the complex forming a mixed-ligand complex, a new e.s.r. spectrum.When X is Cl or Br the additional interaction of the unpaired electron with a single halogen nucleus is observed.The a dipole-dipole coupled dimer and a computer simulation of the ΔMs = 2 absorption of this dimer has been obtained.
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