The Use of α-Trimethylsilyl-α,β-Unsaturated Ketones as 1-Acylethenyl Anion Synthon

DOI: 10.1246/cl.1994.1211

Source and publish data:

Chemistry Letters p. 1211 - 1214 (1994)

Update date:2022-07-29

Topics: Synthon

Authors:

Matsumoto, Kozo

Oshima, Koichiro

Utimoto, Kiitiro

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Article abstract of DOI:10.1246/cl.1994.1211

Treatment of α-trimethylsilyl-α,β-unsaturated ketones with tetrabutylammonium fluoride in the presence of aldehydes provided α-(1-hydroxyalkyl)-α,β-unsaturated ketones in good yields.The reaction proceeded via allenolate.The new method was successfully ap

Full text of DOI:10.1246/cl.1994.1211

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