Thiolate Complexes of Osmium(IV): Preparation of (R=C6F5, C6F4H-4, C6H4F-4 or Ph, R'=Ph; R=C6F5 or C6F4H-4, R'3=Me2Ph) and (X=F or CF3): Crystal Structures of and

DOI: 10.1039/DT9940001819

Source and publish data:

Journal of the Chemical Society, Dalton Transactions p. 1819 - 1824 (1994)

Update date:2022-08-05

Topics:

Authors:

Arroyo, Maribel

Chamizo, Jose A.

Hughes, David L.

Richards, Raymond L.

Roman, Patricia

et al. et al.

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Article abstract of DOI:10.1039/DT9940001819

The diamagnetic osmium(IV) complexes (R=C6F5, C6F4H-4, C6H4F-4, or Ph, R'=Ph; R=C6F5 or C6F4H-4, R'3=Me2Ph) and (X=F or CF3) have been prepared.The complex has an essentially trigonal-bipyramidal structure with an apical PPh3 group ap 2.414(5), mean Os-S_eq, 2.207(7) Angstroem>.The structure of is a somewhat distorted triagonal bipyramid with apical Cl(1-) and PMe2Ph groups .The spectroscopic properties of these compounds are reported and the possibility of isomerism in solution is discussed.

Full text of DOI:10.1039/DT9940001819

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