Metal-assisted fragmentation of N-aryl- and -alkyl-N-trimethylsilylaminosulfur chlorides and N-aryl- and -alkyl-aminosulfur chlorides in the presence of conjugated dienes: Synthesis and reactivity of 2-substituted-3,6-dihydro-1,2-thiazines

DOI: 10.1039/p19960001825

Source and publish data:

Journal of the Chemical Society. Perkin transactions I p. 1825 - 1831 (1996)

Update date:2022-09-26

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Authors:

Bryce, Martin R.

Chesney, Antony

McKelvey, Graham N.

Batsanov, Andrei S.

Howard, Judith A. K.

Anderson, Martin

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Article abstract of DOI:10.1039/p19960001825

N-Alkyl- and -aryl-N-trimethylsilylaminosulfur chlorides 2 and N-aryl- and -alkyl-aminosulfur chlorides 8 fragment in the presence of silver ions and a conjugated diene to yield 2-substituted-3,6-dihydro-1,2-thiarines 6 as the major products, possibly via

Full text of DOI:10.1039/p19960001825

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