Chemical and Pharmaceutical Bulletin p. 985 - 987 (1994)
Update date:2022-08-04
Topics:
Hiroi
Arinaga
Michael addition of bromomalonate carbanions to chiral α-acylvinylic sulfoxides and the subsequent intramolecular alkylation yielded optically active acylcyclopropane derivatives with high enantiomeric excess. Stereochemistry of the product was determined by chemical correlation to a compound of known absolute configuration. The mechanism for the asymmetric induction is deduced on the basis of the stereochemical results obtained.
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