
Tetrahedron Letters p. 6441 - 6444 (1994)
Update date:2022-09-26
Topics:
Thakkar, Kshitij
Cushman, Mark
An unusual oxidative cyclization of chalcones by thallium (III) trinitrate (TTN) to 4-methoxyaurones has been studied. A key feature of this reaction is the introduction of a methoxyl group into the aurone skeleton. Several reactions have been performed to understand the mechanism and regiochemistry of cyclization.
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Doi:10.1021/jo00097a041
(1994)Doi:10.1016/0040-4039(94)88078-6
(1994)Doi:10.1021/jo00100a066
(1994)Doi:10.1124/dmd.113.051862
(2013)Doi:10.1002/chem.201303409
(2014)Doi:10.1016/j.bmc.2016.05.045
(2016)