Diastereoselectivity in cyclopropanation and epoxidation reactions of chiral (E)-crotylsilanes: Asymmetric synthesis of substituted tetrahydrofurans

DOI: 10.1016/S0040-4039(00)78244-X

Source and publish data:

Tetrahedron Letters p. 6453 - 6456 (1994)

Update date:2022-08-03

Topics:

Authors:

Panek, James S.

Garbaccio, Robert M.

Jain, Nareshkumar F.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/S0040-4039(00)78244-X

Functionalized (E)-crotylsilanes 1 bearing a bis-homoallytic hydroxyl group undergo diastereoselective cyclopropanation and epoxidation reactions to produce substituted tetrahydrofurans 3 and 5 respectively after an acid catalyzed heterocyclization.

Full text of DOI:10.1016/S0040-4039(00)78244-X

Products guided by the article

Product name:(E)-(2R,3R)-3-(Dimethyl-phenyl-silanyl)-2-methyl-hex-4-en-1-ol

Cas No:158587-79-2

R&D Labs maybe for 158587-79-2

SOGA ENTERPRISES ASIA GROUP

Contact:+86-633-8332928

Address:No.1,Huanghai Yilu.Rizhao,Shandong
Chongqing Werlchem Fine Chemical Co. Ltd

Contact:+86-23-67521957

Address:NO.15,Fortune Road,Yubei District,401121,Chongqing,China
Changsha Huajing Powdery Material Technological Co., Ltd.

Contact:86-731-88879686

Address:Building 2, West Garden, Main Campus of Central South University, Changsha, Hunan Province, China
Shandong Yuanli Science and Technology Co., Ltd.

Contact:86-0536-6777557

Address:Zhuliu Industiral Park,Changle County
Suzhou Health Chemicals Co., Ltd.

website:http://www.healthchems.com

Contact:13776257979

Address:No. 338, Jingang Avenue,

Relevant to this article

A Highly Efficient Diversification of 2-Amino/Amido-1,3,4-oxadiazole and 1,3,4-Thiadiazole Derivatives via Reagent-Based Cyclization of Thiosemicarbazide Intermediate on Solid-Phase

Doi:10.1021/acscombsci.5b00140
(2015)
The chemistry of 2H-3,1-benzoxazine-2,4(1H)-dione (isatoic anhydride). 19. Direct formation of 2-aminobenzyl alcohols from the reduction of N-substituted isatoic anhydrides

Doi:10.1002/jhet.5570230145
(1986)
Intramolecular Reactivity of Arylcarbenes: Derivatives of o-Tolylcarbene

Doi:10.1021/jo00093a014
(1994)
Single-step substitution of all the α, β-positions in pyrrole: Choice of binuclear versus multinuclear complex of the novel polydentate ligand

Doi:10.1021/ic5000974
(2014)
Development of potent and selective tissue transglutaminase inhibitors: Their effect on TG2 function and application in pathological conditions

Doi:10.1016/j.chembiol.2015.08.013
(2015)
Doi:10.1016/S0277-5387(00)88157-7
(1994)

Article Doi