Diastereoselectivity in cyclopropanation and epoxidation reactions of chiral (E)-crotylsilanes: Asymmetric synthesis of substituted tetrahydrofurans

DOI: 10.1016/S0040-4039(00)78244-X

Source and publish data:

Tetrahedron Letters p. 6453 - 6456 (1994)

Update date:2022-08-03

Topics:

Authors:

Panek, James S.

Garbaccio, Robert M.

Jain, Nareshkumar F.

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Article abstract of DOI:10.1016/S0040-4039(00)78244-X

Functionalized (E)-crotylsilanes 1 bearing a bis-homoallytic hydroxyl group undergo diastereoselective cyclopropanation and epoxidation reactions to produce substituted tetrahydrofurans 3 and 5 respectively after an acid catalyzed heterocyclization.

Full text of DOI:10.1016/S0040-4039(00)78244-X

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