Tetrahedron p. 9467 - 9486 (1995)
Update date:2022-08-03
Topics: Retrosynthetic analysis Purification and characterization Synthesis of the Seco Acid Assembly of Side Chains
Paterson, Ian
Yeung, Kap-Sun
Ward, Richard A.
Smith, Julian D.
Cuimming, John G.
Lamboley, Serge
Swinholide A and isoswinholide A were synthesized in 7 steps from the fully protected seco acid 4. Key steps include: (i) bimolecular acylation, 7 + 10 → 12, (ii) selective hydrolysis of the methyl ester, 16 → 17, and (iii) regioselective macrolactonisati
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