Asymmetric synthesis of both enantiomers of 2.5-hexane diol and 2.6-heptane diol induced by chiral sulfoxides

DOI: 10.1016/S0040-4039(00)77089-4

Source and publish data:

Tetrahedron Letters p. 5297 - 5300 (1994)

Update date:2022-08-04

Topics:

Authors:

Solladie, Guy

Huser, Nathalie

Garcia-Ruano, Jose Luis

Adrio, Javier

Carmen Carreno

Tito, Amelia

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/S0040-4039(00)77089-4

both enantiomers of 2,5-hexane diol and 2,6-heptane diol have been prepared respectively by stereoselective reduction of optically active diketodisulfoxides and ketosulfoxides.

Full text of DOI:10.1016/S0040-4039(00)77089-4

Products guided by the article

Product name:1,6-Bis-((R)-toluene-4-sulfinyl)-hexane-2,5-dione

Cas No:158833-93-3

R&D Labs maybe for 158833-93-3

Du-Hope International Group

website:http://www.np-chem.com

Contact:0086-25-52346877

Address:199, Jian Ye Road, Nanjing, China
Shanghai Yuking Water Soluble Material Tech Co., Ltd

Contact:86-21-68286299

Address:4F, 13B, No. 600, South Xinyuan Road 201306, Shanghai, China
Chengdu King-tiger Pharm-chem. Tech. Co., Ltd

Contact:028-85317716

Address:Tianfu Life Science Park, No. 88 South Keyuan Road, Gaoxin District, Chengdu City, Sichuan Province, PRC.
Accela ChemBio Inc.

Contact:1-858-6993322

Address:9883 Pacific Heights Blvd., Suite H, San Diego
Luoyang Aoda chemical Co.,Ltd.

Contact:+86-379-67518785 67516588

Address:MiaoWan industry district,YanShi City,Henan,China

Relevant to this article

Tetrasubstituted Furans from Novel <3 + 2> Photocycloaddition of Conjugated Acetylenic α-Diketones with Alkenes

Doi:10.1039/c39940001821
(1994)
Synthesis of new sulfonylamido-penicillanic acid sulfones inhibitors of β-lactamases

Doi:10.7164/antibiotics.47.1041
(1994)
Ln[N(SiMe₃)₂]₃-catalyzed cycloaddition of terminal alkynes to azides leading to 1,5-disubstituted 1,2,3-triazoles: New mechanistic features

Doi:10.1039/c3cc42534g
(2013)
(2 S,4 R)-4-hydroxyproline(4-nitrobenzoate): Strong induction of stereoelectronic effects via a readily synthesized proline derivative. Crystallographic observation of a correlation between torsion angle and bond length in a hyperconjugative interaction

Doi:10.1021/jo500367d
(2014)
Synthesis and pharmacological evaluation of new indole derivatives structurally related to thymoxamine

Doi:10.1016/0223-5234(94)90147-3
(1994)
MaxPHOS ligand: PH/NH tautomerism and rhodium-catalyzed asymmetric hydrogenations

Doi:10.1002/adsc.201300662
(2014)

Article Doi