
Journal of the Chemical Society. Perkin transactions I p. 669 - 673 (1996)
Update date:2022-08-04
Topics:
Groundwater, Paul W.
Hughes, David
Hursthouse, Michael B.
Lewis, Rhiannon
Photolysis of 2-fluoro-2′,5′-dimethyldiphenylamine 1a, in ethanol with a medium-pressure mercury lamp, gave a mixture of 1,4-dimethylcarbazole 7 (53%), 8-fluoro-1,4-dimethylcarbazole 2 (11%) and 6-ethoxy-2-fluoro-2′,5′-dimethyldiphenylamine 8 (19%). Photolysis of 4-fluoro-2′,5′-dimethyldiphenylamine 1b gave 6-fluoro-1,4-dimethylcarbazole 25 (35%) and 1,4-dimethylcarbazole 7 (47%).
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