Attempted stereocontrol at C-2' of strigol-type compounds by a Michael reaction/elimination approach

DOI: 10.1016/S0040-4020(98)00076-3

Source and publish data:

Tetrahedron p. 3413 - 3438 (1998)

Update date:2022-08-03

Topics:

Authors:

Roehrig, Susanne

Hennig, Lothar

Findeisen, Matthias

Welzel, Peter

Frischmuth, Katja

Marx, Andreas

Petrowitsch, Tanja

Koll, Peter

Mueller, Dietrich

Mayer-Figge, Heike

Sheldrick, William S.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/S0040-4020(98)00076-3

By a Michael addition/nucleophilic substitution/elimination sequence the stereocontrol at C-2' in strigol-typed compounds is in principle possible. However, the method is unsuitable for practical application since it has been shown that a stereolabile intermediate is involved.

Full text of DOI:10.1016/S0040-4020(98)00076-3

Products guided by the article

Product name:(3S,4S,5S)-5-((1S,2S,5R)-2-isopropyl-5-methyl-cyclohexyloxy)-3-methyl-4-phenylsulfanyl-dihydrofuran-2-one

Cas No:159701-80-1

R&D Labs maybe for 159701-80-1

Xinjiang Zhongtai Chemical Co., Ltd.

Contact:+86-991-8788172

Address:NO.78 XISHAN RD.URUMQI，CHINA
Jiangsu Chiatai Qingjiang Pharmaceutical Co.,Ltd

Contact:+86-517-86283327

Address:9 North Hantai Road, Huaian, China
Daicel Chiral Technologies (China)CO.,LTD

Contact:021-5046-0086*8

Address:Part C, FL 5, the 16th Building, No. 69, XiYa Road, WaiGaoQiao Free Trade Zone, Shanghai, 200131, P.R.China
MS( MAOSHENG )Chemical CO.,LTD

Contact:+86-519-82726678.82726378

Address:TAOXI INDUSTRY ZONE JINTAN
Shanghai Yuantai Chemical Products Co., Ltd

Contact:021--66129803

Address:Chengyin Road,Shanghai,China

Relevant to this article

An Electrochemically Promoted, Nickel-Catalyzed Mizoroki-Heck Reaction

Doi:10.1021/acscatal.9b02230
(2019)
Phenalenone-type phytoalexins from Musa acuminata synthesis of 4-phenyl-penalenones

Doi:10.1016/S0040-4020(01)85707-0
(1994)
A short synthesis of (+)-tortuosamine

Doi:10.1016/0040-4039(94)88266-5
(1994)
A simple, efficient thermally promoted protocol for Huisgen-click reaction catalyzed by CuSO₄·5H₂O in water

Doi:10.1016/j.tetlet.2014.02.108
(2014)
Selective detection of carbohydrates and their peptide conjugates by esi-ms using synthetic quaternary ammonium salt derivatives of Phenylboronic acids

Doi:10.1007/s13361-014-0857-4
(2014)
Aminothiazole derivative. I. A convenient synthesis of monocyclic and condensed 5-aminothiazole derivatives

Doi:10.1002/jhet.5570310432
(1994)

Article Doi