Attempted stereocontrol at C-2' of strigol-type compounds by a Michael reaction/elimination approach

DOI: 10.1016/S0040-4020(98)00076-3

Source and publish data:

Tetrahedron p. 3413 - 3438 (1998)

Update date:2022-08-03

Topics:

Authors:

Roehrig, Susanne

Hennig, Lothar

Findeisen, Matthias

Welzel, Peter

Frischmuth, Katja

Marx, Andreas

Petrowitsch, Tanja

Koll, Peter

Mueller, Dietrich

Mayer-Figge, Heike

Sheldrick, William S.

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Article abstract of DOI:10.1016/S0040-4020(98)00076-3

By a Michael addition/nucleophilic substitution/elimination sequence the stereocontrol at C-2' in strigol-typed compounds is in principle possible. However, the method is unsuitable for practical application since it has been shown that a stereolabile intermediate is involved.

Full text of DOI:10.1016/S0040-4020(98)00076-3

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