A General Preparative Method for Carbonyl-Protected γ-Lithioketones via Reductive Lithiation. Synthetic Uses of the Bishomoenolate Equivalents

DOI: 10.1016/S0040-4020(01)85652-0

Source and publish data:

Tetrahedron p. 11569 - 11584 (1994)

Update date:2022-08-04

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Authors:

Cohen, Theodore

Zhang, Birong

Cherkauskas, John P.

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Article abstract of DOI:10.1016/S0040-4020(01)85652-0

The mixed cuprates, generated by reductive lithiation of bis(phenylthio)acetals using lithium 4,4'-di-tert-butylbiphenylide (LDBB), followed by addition of cuprous bromide-dimethyl sulfide complex, undergo conjugate addition to enones in the presence of t

Full text of DOI:10.1016/S0040-4020(01)85652-0

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