Diastereoselectivity in the O-H insertion reactions of rhodium carbenoids derived from phenyldiazoacetates of homochiral alcohols

DOI: 10.1016/S0040-4039(00)78227-X

Source and publish data:

Tetrahedron Letters p. 5949 - 5952 (1994)

Update date:2022-08-03

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Authors:

Aller Aller

Cox Cox

Miller Miller

Moody Moody

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Article abstract of DOI:10.1016/S0040-4039(00)78227-X

Rhodium(II) acetate catalysed decomposition of the phenyldiazoacetates 3 in the presence of alcohols (methanol, propan-2-ol, tert-butanol) led to the O-H insertion products 4 - 6 in varying yields; the diastereomeric excess of the product ranged from 5-53%.

Full text of DOI:10.1016/S0040-4039(00)78227-X

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