New route to 1-(5-imidazolyl)ribofuranoid glycals from ribofuranosyl chloride and 5-lithio-imidazole

DOI: 10.1248/cpb.43.152

Source and publish data:

Chemical and Pharmaceutical Bulletin p. 152 - 155 (1995)

Update date:2022-08-03

Topics:

Authors:

Harusawa

Kawabata

Murai Murai

Yoneda Yoneda

Kurihara

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Article abstract of DOI:10.1248/cpb.43.152

Reaction of ribofuranosyl chlorides with 2 eq of 5-lithio-imidazole afforded 1-(5-imidazolyl)ribofuranoid glycals in good yields. Hydrolysis of the glycal (3) with hydrochloric acid led to 4-(5-hydroxymethylfuran-2-yl)imidazole (7), which contains both hy

Full text of DOI:10.1248/cpb.43.152

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