Journal of the Chemical Society. Chemical communications p. 331 - 332 (1995)
Update date:2022-07-30
Topics:
Wehman, Petra
Ruelke, Richard E.
Kaasjager, Vincent E.
Kamer, Paul C. J.
Kooijman, Huub
et al.
The new, multifunctional, semi-labile phosphorus-bisnitrogen ligand N-(2-diphenylphosphinobenzylidene)-2-(2-pyridyl)ethylamine, PNN, stabilises methyl(chloro)-, η1-allyl(chloro)-, dichloro- and bis(tetrafluoroborate)palladium(II) PNN complexes in a terdentate coordination fashion, resulting in ionic palladium complexes, as well as an unprecedented palladium(0) PNN complex as is evidenced from 1H, 13C, 31P and 15N NMR spectra and an X-ray structural analysis of <(PNN)PdMe>+
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