Thermal Rearrangement of Enantioenriched α-Hydroxy Imines -II. Formal Synthesis of (-)-Perhydrohistrionicotoxin.

DOI: 10.1016/0040-4039(95)00681-2

Source and publish data:

Tetrahedron Letters p. 4063 - 4064 (1995)

Update date:2022-09-26

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Authors:

Compain, Philippe

Gore, Jacques

Vatele, Jean-Michel

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Synthesis of (+)-1-benzyl-1-azaspiro<5.5>undecan-7-one 6 from α-ketol 1, via a 1,2-suprafacial chirality transfer, is described.

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