Organometallic Macrocycle Chemistry. 4. Synthesis and Reactions of [RuX(CS)(PPh3)([9]aneS3)]ClO4 (X=H, Cl, SCN, SC6H4Me-4; [9]aneS3=1,4,7-Trithiacyclononane)

Article abstract of DOI:10.1021/ic00118a029

The reactions of [RuCl2(OH2)(CS)(PPh3)2] and [RuHCl(CS)(PPh3)3] with 1,4,7-trithiacyclononane ([9]aneS3) provide the thiacrown complexes [RuX(CS)(PPh3)([9]aneS3)](+) (X=Cl, H; isolated as ClO4(-) salts). [RuCl(CS)(PPh3)([9]aneS3)]ClO4 reacts with potassiu