Organometallic Macrocycle Chemistry. 4. Synthesis and Reactions of [RuX(CS)(PPh3)([9]aneS3)]ClO4 (X=H, Cl, SCN, SC6H4Me-4; [9]aneS3=1,4,7-Trithiacyclononane)

DOI: 10.1021/ic00118a029

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(1995)

Update date:2022-07-31

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Authors:

Hector, Andrew L.

Hill, Anthony F.

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Article abstract of DOI:10.1021/ic00118a029

The reactions of [RuCl2(OH2)(CS)(PPh3)2] and [RuHCl(CS)(PPh3)3] with 1,4,7-trithiacyclononane ([9]aneS3) provide the thiacrown complexes [RuX(CS)(PPh3)([9]aneS3)](+) (X=Cl, H; isolated as ClO4(-) salts). [RuCl(CS)(PPh3)([9]aneS3)]ClO4 reacts with potassiu

Full text of DOI:10.1021/ic00118a029

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Product name:[Ru(4-thiocresolate)(CS)P(C₆H₅)3(1,4,7-trithiacyclononane)]PF₆

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