Ring Contraction vs Fragmentation in the Intramolecular Reactions of 3-O-(Trifluoromethanesulfonyl)pyranosides. Efficient Synthesis of Branched-Chain Furanosides

DOI: 10.1021/jo00119a011

Source and publish data:

Journal of Organic Chemistry p. 4353 - 4358 (1995)

Update date:2022-08-06

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Authors:

Kassou, Mohamed

Castillon, Sergio

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Article abstract of DOI:10.1021/jo00119a011

Intramolecular reactions of several methyl 3-O-triflylpyranosides of gluco, manno, galacto, and arabino(2-deoxy-gluco) configuration are studied.Triflates 1b-6b, of gluco, manno, and 2-deoxy-gluco configuration, give rise to ring-contraction products (bra

Full text of DOI:10.1021/jo00119a011

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