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Stereoselective Synthesis of Rare (D and L) Saccharides by a Facile Intramolecular Rearrangement of Hemiacetal Heptanolactone Alcohols

DOI: 10.1039/c39930000062

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 62 - 63 (1993)

Update date:2022-08-04

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Authors:

Mereyala, Hari BabuMereyala, Hari Babu

Guntha, SreenivasuluGuntha, Sreenivasulu

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Article abstract of DOI:10.1039/c39930000062

The hemiacetal heptanolactone alcohols 2a, b, c and d undergo a facile acid catalysed, stereospecific intramolecular rearrangement to yield the rare D and L saccharides 3, 4, 5 and 6 respectively.

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