Regiospecific 4,6-functionalization of pyranosides via dimethylboron bromide-mediated cleavage of phthalide orthoesters

DOI: 10.1021/ja00106a021

Source and publish data:

Journal of the American Chemical Society p. 177 - 183 (1995)

Update date:2022-09-26

Topics: Functionalization Cleavage Selective Reaction Regiospecific Pyranosides Mediated Reaction

Authors:

Arasappan, Ashok

Fuchs Fuchs

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Article abstract of DOI:10.1021/ja00106a021

An efficient strategy for regiocontrolled differentiation of the 4,6-positions of pyranosides has been developed using dimethylboron bromide-mediated cleavage of phthalide orthoesters. The reaction proceeds under mild conditions, is tolerant of additional

Full text of DOI:10.1021/ja00106a021

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