Chemical, Computational, and Structural Studies of Dimeric (Pentamethylcyclopentadienyl)zirconium Thiolate and Alkoxide Complexes

DOI: 10.1021/ic00115a005

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(1995)

Update date:2022-08-02

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Authors:

Heyn, Richard H.

Stephan, Douglas W.

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Article abstract of DOI:10.1021/ic00115a005

The compounds [Cp(*)Zr(SR)2(μ2-SR)]2 (R = Bz (6), Et (7)) are prepared via reaction of Cp(*)ZrCl3 with 3 equiv of the respective sodium thiolate. The NMR data of 6 are consistent with a symmetric dimer in which two thiolate ligands bridge two Zr centers a

Full text of DOI:10.1021/ic00115a005

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