Stereocontrolled Synthesis of Spirodihydrouracil Nucleoside

DOI: 10.1016/S0957-4166(00)86299-0

Source and publish data:

Tetrahedron Asymmetry p. 2233 - 2240 (1994)

Update date:2022-08-03

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Authors:

Sano, Hiromi

Mio, Shigeru

Kitagawa, Junko

Sugai, Soji

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Article abstract of DOI:10.1016/S0957-4166(00)86299-0

Synthesis of the spiro-dihydrouracil derivative of (+)-hydantocidin (2) is described.The pivotal step is a Lewis acid-mediated C-glycosidation of the protected D-psicose 3 with trimethylsilyl cyanide, which proceeded in good yield and β-selectivity.Synthe

Full text of DOI:10.1016/S0957-4166(00)86299-0

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