Journal of Organometallic Chemistry p. C15 - C18 (1995)
Update date:2022-08-03
Topics:
Rooy, Annemiek van
Kamer, Paul C. J.
Leeuwen, Piet W. N. M. van
Veldman, Nora
Spek, Anthony L.
The crystal structure and characterization in solution are described for a very regioselective hydroformylation catalyst, RhH(CO)2(diphosphite) with <2(3,3',5,5'-tetra-tert-butyl-1,1'-biphenyl-2,2'-diylphosphite),2'(bis(4-Cl-phenyl)phosphite)-3,3,5',5'-tetra-tert-butyl-1,1'-biphenyl> as the diphosphite.The complex is formed under CO-H2 pressure from Rh(CO)2Acac and has a distorted TBP geometry with both phosphorus atoms in equatorial positions.Keywords: Rhodium; Diphosphite; Hydroformylation; Catalysis; Crystal structure
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(1995)
