Malonate Radical Cyclisations of Methylenecyclopropane Derivatives

DOI: 10.1016/S0040-4020(01)89430-8

Source and publish data:

Tetrahedron p. 11289 - 11302 (1994)

Update date:2022-08-03

Topics: Derivatives Radical Cyclisation Experimental

Authors:

Destabel, Christine

Kilburn, Jeremy D.

Knight, John

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Article abstract of DOI:10.1016/S0040-4020(01)89430-8

Cyclisations of various methylenecyclopropyl substituted malonate radicals have been studied.Radicals derived from malonates 4 and 9 underwent exclusive 5-exo cyclisation onto the methylenecyclopropane alkene, followed by opening of the resulting cyclopro

Full text of DOI:10.1016/S0040-4020(01)89430-8

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