
Tetrahedron Letters p. 2469 - 2472 (1995)
Update date:2022-08-02
Topics:
Abarbri
Parrain
Duchene
The palladium catalysed coupling of organozinc or organotin reagents with 3-iodobut-2(or 3)-enoic acid is stereoselective and affords Z (or E)-3-methylalk-2-enoic acids. The method was applied to the synthesis of the E and Z stereoisomers of ocimenones and pseudo-tagetones.
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