Novel Thermal Cyclisation of o-Methylstyrylalkynes to give 2-Alkenylnaphthalenes

DOI: 10.1016/0040-4039(94)02445-H

Source and publish data:

Tetrahedron Letters p. 1303 - 1306 (1995)

Update date:2022-08-04

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Authors:

Aitken, R. Alan

Boeters, Christine

Morrison, John J.

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Article abstract of DOI:10.1016/0040-4039(94)02445-H

Formation of o-methylstyrylalkynes by flash vacuum pyrolysis of the corresponding stabilised phosphorus ylides at 900 deg C is accompanied by unexpected cyclisation to give 2-alkenylnaphthalenes and deuterium labelling has been used to elucidate the mechanisms involved.

Full text of DOI:10.1016/0040-4039(94)02445-H

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